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Unveiling Zn Incorporation in CuInS2 Quantum Dots: X-ray and Optical Analysis of Doping Effects, Structural Modifications, and Surface Passivation

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dc.contributor.affiliation000000041762408X
dc.contributor.affiliationMadrid Institute for Advanced Studies IMDEA Nanoscience, Ciudad Universitaria de Cantoblanco, Calle Faraday 9, Madrid, 28049, Spain; Departamento de Química, Universidad Autónoma de Madrid, Ciudad Universitaria de Cantoblanco, Calle Francisco Tomás y Valiente 7, Madrid, 28049, Spain; Departamento de Química Analítica, Química Física e Ingeniería Química, Universidad de Alcalá, Alcalá de Henares, Madrid, 28805, Spain; Departamento de Química Física Aplicada, Universidad Autónoma de Madrid, Ciudad Universitaria de Cantoblanco, Calle Francisco Tomás y Valiente 7, Madrid, 28049, Spain; Instituto de Física Gleb Wataghin, Universidade Estadual de Campinas─UNICAMP, Campinas, São Paulo, 13083-852, Brazil; Grupo de Pesquisa Química de Materiais, Departamento de Ciências Naturais, Universidade Federal de São João Del-Rei, São João Del-Rei, Minas Gerais, 36301-160, Brazil; Laboratório de Nanotecnologia e Energia Solar, Chemistry Institute, University of Campinas─UNICAMP, Campinas, São Paulo, 13083-970, Brazil; CELLS-ALBA Synchrotron Light Source, Cerdanyola del Vallès, Barcelona, 08290, Spain; Chemistry, School of Natural and Environmental Sciences, Newcastle University, Newcastle upon Tyne, NE1 7RU, United Kingdom; Faculty of Physics, Adam Mickiewicz University, ul. Uniwersytetu Poznańskiego 2, Poznań, 61-614, Polanden
dc.contributor.authorBurgos-Caminal A.
dc.contributor.authorVale B.R.C.
dc.contributor.authorFonseca A.F.V.
dc.contributor.authorHidalgo J.F.
dc.contributor.authorCollet E.P.P.
dc.contributor.authorGarcía L.
dc.contributor.authorGarcia-Orrit S.
dc.contributor.authorArnay I.
dc.contributor.authorSimonelli L.
dc.contributor.authorNogueira A.F.
dc.contributor.authorSchiavon M.A.
dc.contributor.authorPenfold T.J.
dc.contributor.authorPadilha L.A.
dc.contributor.authorGawelda W.
dc.contributor.authorVega-Mayoral, Victor
dc.contributor.authorCabanillas González, Juan
dc.date.accessioned2026-04-14T10:00:41Z
dc.date.available2026-04-14T10:00:41Z
dc.date.issued2026
dc.format.mimetypeapplication/pdfen
dc.identifier.doi10.1021/acs.chemmater.5c01878
dc.identifier.urihttps://hdl.handle.net/20.500.12614/4275
dc.journal.titleChemistry of Materialsen
dc.language.isoenen
dc.page.initial2601
dc.relation.projectIDTEMPThe steady-state XAS experiments were performed at the CL\u00C6SS beamline at ALBA Synchrotron within the Proposal 2021095311. We would like to greatly acknowledge the help and support of the CL\u00C6SS beamline staff in the preparation and execution of XAS experiments, which contributed to the results presented here. The authors would also like to thank Dr. Reinhold Wannemacher and Luis Colmenar for their help with TRPL and PLQY measurements, respectively, at IMDEA Nanoscience. A.B.-C. is grateful to the Spanish \u201CMinisterio de Universidades\u201D and the \u201CPlan de Recuperacio\u0301n, Transformacio\u0301n y Resiliencia\u201D, as well as the UAM, for his \u201CMargarita Salas\u201D grant (ref CA1/RSUE/2021-00809). In addition, he receives funding from the European Union\u2019s Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie agreement No. 101034431 and from the \u201CSevero Ochoa\u201D Programme for Centres of Excellence in R&D (CEX2020-001039S/AEI/10.13039/501100011033). W.G. acknowledges funding from Spanish Ministry of Universities through \u201CAyudas Beatriz Galindo\u201D (BEAGAL18/00092), Regional Government of Madrid and Universidad Auto\u0301noma de Madrid through \u201CProyectos de I+D para Investigadores del Programa Beatriz Galindo\u201D grant (ref SI2/PBG/2020-00003), Spanish Ministry of Science, Innovation and Universities through \u201CProyectos de I+D+i 2019\u201D grant (ref PID2019-108678GB-I00), and \u201CProyectos de I+D+i 2022\u201D grant (ref PID2022-140257NB-I00). BRCV and LAP thank Sa\u0303o Paulo Research Foundation, FAPESP, under grants 2018/15574-6 and 2022/06470-8. B.R.C.V. also thanks FAPESP for the postdoctoral scholarship under grants 2020/16077-6 and 2024/01722-4. A.F.V.F. thanks FAPESP under the grant 2023/10395-4. A.F.N. acknowledges the support from the FAPESP (grant no. 2017/11986-5) and Shell and the strategic importance of the support given by ANP (Brazil\u2019s National Oil, Natural Gas, and Biofuels Agency). MAS acknowledges the support from the CNPq and FAPEMIG (grant no. APQ-02598-23). J.C.-G. acknowledges the MICINN-FEDER (Nos.: PID2021-128313OB-I00 and PID2024-162801OB-I00), support from the Regional Government of Madrid (TEC-2024/TEC-459 SYNMOLMAT-CM), a Research Consolidation Grant (No. CNS2022-36191) and project PDC202-314587-1I00 from the Spanish Ministry of Science and Innovation. V.V.-M. acknowledges grants TED2021-131906A-100 and RYC2022-035200-I funded by the Spanish Ministry of Science, Innovation and Universities (10.13039/501100011033) and support from the Regional Government of Madrid (2019-T2/IND-12737 and 2024-T1/TEC-31349). S.G.-O. is grateful to the Spanish Ministry of Science and Innovation for a Ph.D. grant (FPI, PRE2019-09345). This work was also partially funded by the regional government of Madrid (Spain) through the Tecnologias 2024 program, project MATRIX-CM (TEC-2024/TEC-85).
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España
dc.rights.accessRightsopen accessen
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.titleUnveiling Zn Incorporation in CuInS2 Quantum Dots: X-ray and Optical Analysis of Doping Effects, Structural Modifications, and Surface Passivationen
dc.typeresearch articleen
dc.type.hasVersionVoRen
dc.volume.number38
dspace.entity.typePublication
relation.isAuthorOfPublication4dde3a68-62af-4228-9625-6d6f0365d8f7
relation.isAuthorOfPublicationb69e859e-7399-4cfb-a8cb-060cd29c87f6
relation.isAuthorOfPublication.latestForDiscovery4dde3a68-62af-4228-9625-6d6f0365d8f7

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