Browsing by Funding "Computation time at CINECA supercomputing centers is gratefully acknowledged. The X-ray absorption measurements were performed on the EPFL/PSI X-Treme beamline at the Swiss Light Source, Paul Scherrer Institut, Villigen, Switzerland, at the BOREAS beamline of the Alba Synchrotron Radiation Facility, Cerdanyola del Vallés, Spain, and at the ID32 beamline of the European Synchrotron Radiation Facility, Grenoble, France. We acknowldege funding from the National Research Council (CNR) within the CNR/CAS Cooperative Programme project Advanced characterization methods for the study of rare-earth single-ion magnets on oxide substrates from the Czech Academy of Sciences (Mobility Plus Project No. CNR-19-03), and from the Swiss National Science Foundation (200020_176932 and 200021_175941). ICN2 was funded by the CERCA Programme/Generalitat de Catalunya and supported by the Spanish Ministry of Economy and Competitiveness, MINECO (grant nos. SEV-2017-0706 and PID2019-107338RB-C65/AEI/10.13039/501100011033). IMDEA Nanociencia acknowledges support from the Severo Ochoa Programme for Centres of Excellence in R&D (MINECO, grant SEV-2016-0686). We acknowledge P. Orgiani (CNR-SPIN) for the loan of some of the Nb-doped STO single crystals used in these studies and M. Retegan (ESRF) for assistance with the use of Crispy and Quanty."

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